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另外 / 另

lìngwài / lìng

Similarities

Both 另外 and 另 mean “another” or “other”, and both can be a pronoun or an adverb.

()()(biān)(shuō)(xiè)(xie)()(biān)(cóng)(shǒu)()()(chū)(lìng)(wài)()(běn)(shū)
While thanking them, he took out another book.
()()(biān)(shuō)(xiè)(xie)()(biān)(cóng)(shǒu)()()(chū)(lìng)()(běn)(shū)
While thanking them, he took out another book.
Both sentences mean the same thing.

1. As pronouns

另外 + Number + Noun · 另外的 + Noun
另 + Number + Noun
另一本书 is correct; 另的书 is not — 另 does not take 的.

2. As adverbs

(Lìng)(zhǎo)(bié)(rén)
Find someone else.
(Lìng)(mǎi)()()
Buy another one.
(Lìng)(wài)()(gōng)()(shǎo)(xīn)(de)(cái)(liào)
Additionally provided a good deal of new material.
另 usually goes with monosyllabic verbs; 另外 works with almost any verb.

3. As a conjunction

(Dōng)()(yīng)(gāi)(zhù)()(duō)(chī)(shuǐ)(guǒ)
In winter you should eat more fruit.
(Lìng)(wài)(hái)(yào)()(de)(duō)()(shuǐ)
Besides, remember to drink more water.
另 cannot be used this way.

Quick comparison

另外
pronoun, adverb and conjunctionpronoun and adverb
另外的… is possible另的… is not
with many kinds of verbusually with monosyllabic verbs
另外 is the common, versatile form. 另 is the shorter one: 另一本, 另找, 另买.